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61.
62.
Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for 207Pb/206Pb and 208Pb/206Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for 207Pb/206Pb (208Pb/206Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for 207Pb/206Pb and 208Pb/206Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores. 相似文献
63.
The lateral deflection of a cylindrical diaphragm wall and the associated ground movement induced by deep excavation are analyzed by performing site instrumentations and numerical analyses in the coastal area of Korea. Wall lateral deflection, rebar stress, and pore water pressure were measured and analyzed in eight directions. Variations of soil properties with the decrease of confining pressure are compared by performing various in situ tests before ad after excavation. To calculate the wall lateral deflection accurately, the effects of small strain nonlinearity, confining pressure, and the hysteresis loading/unloading loop developed during excavation are considered in the proposed numerical analysis. By comparing numerical results with measured ones, the importances of considering small strain nonlinearity and confining pressure reduction in the nonlinear (FEM) are emphasized. Also, the effects of wall stiffness on the performance of cylindrical diaphragm walls are studied for future similar excavation in the coastal area. 相似文献
64.
Characterization of chromophoric dissolved organic matter (CDOM) in the Baltic Sea by excitation emission matrix fluorescence spectroscopy 总被引:11,自引:0,他引:11
Piotr Kowalczuk Joanna Sto-Egiert William J. Cooper Robert F. Whitehead Michael J. Durako 《Marine Chemistry》2005,96(3-4):273-292
Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and aCDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient. 相似文献
65.
Santa Monica Bay is an open coastal embayment located directly seaward of Los Angeles, California. The Bay provides vital economic value through its water-dependent activities, such as swimming, diving, boating, and fishing. An increase from 100,000 residents in 1900 to 10 million in 2000 has imposed numerous environmental stressors on the Bay, including urbanization of the watershed. Pollutant discharges into the Bay increased throughout the early part of the century, but declined following passage of the Clean Water Act in 1972. Since that time, the predominant source of pollutant inputs has changed from point sources to non-point urban runoff. To assess how present-day and historical pollution interact to affect the environmental quality of Santa Monica Bay, three organizations collaborated on a multi-disciplinary study in 1997, towards which this volume is focused. This paper details the temporal patterns of anthropogenic influence on Santa Monica Bay to provide context for the papers that follow. 相似文献
66.
Ben K. H. Soon Steve Scheding Hyung-Kuen Lee Hung-Kyu Lee Hugh Durrant-Whyte 《GPS Solutions》2008,12(4):261-271
This paper presents a simple and effective approach that incorporates single-frequency, L1 time-differenced GPS carrier phase
(TDCP) measurements without the need of ambiguity resolution techniques and the complexity to accommodate the delayed-state
terms. Static trial results are included to illustrate the stochastic characteristics and effectiveness of the TDCP measurements
in controlling position error growth. The formulation of the TDCP observation model is also described in a 17-state tightly-coupled
GPS/INS iterative, extended Kalman filter (IEKF) approach. Preliminary land vehicle trial results are also presented to illustrate
the effectiveness of the TDCP which provides sub-meter positional accuracies when operating for more than 10 min. 相似文献
67.
Many Gulf of Mexico estuaries have low ratios of water volume to bottom surface area, and benthic processes in these systems
likely have a major influence on system structure and function. The purpose of this study was to determine the spatiotemporal
distribution of biomass and community composition of subtidal benthic microalgal (BMA) communities in Galveston Bay, TX, USA,
compare BMA community composition and biomass to phytoplankton in overlying waters, and estimate the potential contribution
of BMA to the trophodynamics in this shallow, turbid, subtropical estuary. The estimates of BMA biomass (mean = 4.21 mg Chl
a m−2) for Galveston Bay were within the range of the reported values for similar Gulf of Mexico estuaries. BMA biomass in the
central part of the bay was essentially homogeneous, whereas biomass at the seaward and upper bay ends of the transect were
significantly lower. Peridinin, fucoxanthin, and alloxanthin were the three carotenoids with the highest concentrations, with
fucoxanthin having the highest mean concentration (1.82 mg m−2). The seaward and landward ends of the transect differed from the central region of the bay with respect to the relative
abundances of chlorophytes, cyanobacteria, and photosynthetic bacteria. Benthic microalgal community composition also showed
a gradual shift over time due to changes in the relative abundances of photosynthetic bacteria, cryptophytes, dinoflagellates,
and cyanobacteria. Major changes in community composition occurred in the spring months (March to April). On an areal basis,
BMA biomass in Galveston Bay occurred at minor concentrations (16.5%) relative to phytoplankton. Furthermore, the concentrations
of carotenoid pigments for phytoplankton and BMA (fucoxanthin, alloxanthin, and zeaxanthin) were correlated (r = 0.48 to 0.61), suggesting a close linkage between microalgae in the water column and sediments. The contribution of BMA
to the primary productivity of the deeper waters (>2 m) of Galveston Bay is probably very small in comparison to shallower
waters along the bay margins. The significant similarities in the community composition of phytoplankton and BMA illustrate
the potential importance of deposition and resuspension processes in this turbid, shallow estuary. 相似文献
68.
Estimating hydraulic conductivity using grain-size analyses, aquifer tests, and numerical modeling in a riverside alluvial system in South Korea 总被引:2,自引:0,他引:2
Jae-Yeol Cheong Se-Yeong Hamm Hyoung-Soo Kim Eun-Joung Ko Kyounghee Yang Jeong-Hwan Lee 《Hydrogeology Journal》2008,16(6):1129-1143
Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10?4 m s?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10?4 m s?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10?6 m s?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system. 相似文献
69.
Summary During the first pilot phase of the International Cirrus Experiment (ICE) in September/October 1987 radiation measurements were carried out above and below broken cloud fields over the German Bight. Analyses of the measurements of 25.9.1987 (broken cumulus cloud field) showed an unexpected high absorption of solar radiation but not those of 28.9.1987 (stratocumulus/stratus cloud field). This might be explained by a partial negligence of cloud side factor under the viewing geometry of the pyranometer and other reasons. The light guide effect (leakage) within holes can account for the depletion of cloud reflectance and the enhancement of cloud transmittance at large cloud cover, as observed during the measurements on 28.9.1987. The fluctuation of the irradiances, which can be characterized by the intermittency parameter, has been related to the corresponding cloud cover by a regression equation. On the condition of similarity, this scaling parameter derived from sample measurements could be extrapolated to that of the whole cloud field. Thus, the estimation of the irradiance spectrum for the whole cloud field may be possible, from samples taken with aircraft and imaging data.With 5 Figures 相似文献
70.
We report the results of an experiment that produced a residue which closely matches the hydrocarbon component of the Murchison carbonaceous chondrite. This experiment suggests that the parent material of the meteoritic component originated as polycyclic aromatic hydrocarbon species in carbon stars during their later stages of evolution. The experiments also indicate that the pathway from those formation sites to eventual incorporation into the meteorite parent body involved hydrogenation in a plasma in the solar nebula or in H II regions prior to the solar nebula. This model is consistent with what is known about the meteoritic hydrocarbon component including deuterium abundance, the observation of cosmic infrared emission bands best attributed to polycyclic aromatic hydrocarbon molecules, and the inherent stability of these molecules that allows their formation in stars and subsequent survival in the interstellar medium. 相似文献